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  • 687510 - Chloro[2-dicyclohexyl(2′,4′,6′-trisopropylbiphenyl)phosphine]gold(I)

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Chloro[2-dicyclohexyl(2′,4′,6′-trisopropylbiphenyl)phosphine]gold(I)

687510

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Synonym: 2-Dicyclohexylphosphino-2′,4′,6′-triisopropylbiphenyl gold(I) chloride

  • CAS Number: 854045-94-6

  • Empirical Formula (Hill Notation): C33H49AuClP

  • Molecular Weight: 709.14

  • MDL number: MFCD09842765

Chloro[2-dicyclohexyl(2′,4′,6′-trisopropylbiphenyl)phosphine]gold(I)
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Description

Packaging

1 g in glass btl

250 mg in glass btl

Application

Gold Catalysts — 21st Century ′Gold Rush′

Catalyst for:
• Michael addition and intramolecular hydroalkylation reactions
• Cascade cyclization of diynes
• Hydroarylation of allenes via a highly regioselective carbon-carbon bond formation producing six-membered rings
• Alkyne cyclizations in a Holey catalytic environment

Price and Availability


Documents

Certificate of Analysis

Structure Search
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Safety Information

WGK Germany3
Technical information & documentation associated with this product is available in the Safety & Documentation tab.

Related Content

Gold Catalyst in Chemical Synthesis

Introduction Hashmi, Toste, Echavarren, and Haruta, among others, have fueled the advance of gold into the forefront of transition metal catalysis.1,2 Phosphine ligated gold(I) complexes have risen a...

References

Xiao, Y.-P.; et al. Beilstein J. Org. Chem. 7, 1100, (2011)

Hirano, K.; et al. J. Org. Chem. 76, 1212, (2011)

Watanabe, T.; et al. Org. Lett. 9, 4821, (2007)

Ochida, A.; et al. J. Am. Chem. Soc. 128, 16486, (2006)


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